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Multipass spectroscopic absorption cells
Multiple-pass or long path absorption cells are commonly used in spectroscopy to measure low-concentration components or to observe weak spectra in gases or liquids. Several important advances were made in this area beginning in the 1930s, and research into a wide range of applications continues to the present day.
==Functional Overview==
Generally the goal of this type of sample cell is to improve detection sensitivity by increasing the total optical path length that travels through a small, constant sample volume. In principle, a longer path length results in greater detection sensitivity. Focusing mirrors must be used to redirect the beam at each reflection point, resulting in the beam being restricted to a predefined space along a controlled path until it exits the optical cavity. The output of the cell is the input of an optical detector (a specialized type of transducer), which senses specific changes in the properties of the beam that occur during interaction with the test sample. For instance, the sample may absorb energy from the beam, resulting in an attenuation of the output that is detectable by the transducer. Two conventional multipass cells are the White cell and Herriott cell.
抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』
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